A Glossary of Battery Terms
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Ampere-Hour
-- One ampere-hour is equal to a current of
one ampere flowing for one hour. A unit-quantity of electricity
used as a measure of the amount of electrical charge that may
be obtained from a storage battery before it requires recharging.
Ampere-Hour Capacity
-- The number of ampere-hours which can be delivered by a storage
battery on a single discharge. The ampere-hour capacity of a battery
on discharge is determined by a number of factors, of which the
following are the most important: final limiting voltage; quantity
of electrolyte; discharge rate; density of electrolyte; design
of separators; temperature, age, and life history of the battery;
and number, design, and dimensions of electrodes.
Anode
-- In a primary or secondary cell, the metal electrode that gives
up electrons to the load circuit and dissolves into the electrolyte.
Aqueous Batteries
-- Batteries with water-based electrolytes.
Available Capacity
-- The total battery capacity, usually expressed in ampere-hours
or milliampere-hours that are available to perform work. This
depends on factors such as the endpoint voltage, quantity and
density of electrolyte, temperature, discharge rate, age, and
the life history of the battery.
Battery
-- A device that transforms chemical energy into electric energy.
The term is usually applied to a group of two or more electric
cells connected together electrically. In common usage, the term
"battery" is also applied to a single cell, such as
a household battery.
Battery Types
-- There are, in general, two type of batteries: primary batteries,
and secondary storage or accumulator batteries. Primary types,
although sometimes consisting of the same active materials as
secondary types, are constructed so that only one continuous or
intermittent discharge can be obtained. Secondary types are constructed
so that they may be recharged, following a partial or complete
discharge, by the flow of direct current through them in a direction
opposite to the current flow on discharge. By recharging after
discharge, a higher state of oxidation is created at the positive
plate or electrode and a lower state at the negative plate, returning
the plates to approximately their original charged condition.
Battery Capacity
-- The electric output of a cell or battery on a service test
delivered before the cell reaches a specified final electrical
condition and may be expressed in ampere-hours, watt-hours, or
similar units. The capacity in watt-hours is equal to the capacity
in ampere-hours multiplied by the battery voltage.
Battery Charger
-- A device capable of supplying electrical energy to a battery.
Battery-Charging
Rate -- The current expressed in amperes at which a storage
battery is charged.
Battery Voltage,
final -- The prescribed lower-limit voltage at which battery
discharge is considered complete. The cutoff or final voltage
is usually chosen so that the useful capacity of the battery is
realized. The cutoff voltage varies with the type of battery,
the rate of discharge, the temperature, and the kind of service
in which the battery is used. The term "cutoff voltage"
is applied more particularly to primary batteries, and "final
voltage" to storage batteries. Synonym: Voltage, cutoff.
Ci
-- The rated capacity, in ampere-hours, for a specific, constant
discharge current (where i is the number of hours the cell can
deliver this current). For example, the C5 capacity is the ampere-hours
that can be delivered by a cell at constant current in 5 hours.
As a cell's capacity is not the same at all rates, C5 is usually
less than C20 for the same cell.
Capacity
-- The quantity of electricity delivered by a battery under specified
conditions, usually expressed in ampere-hours.
Cathode
-- In a primary or secondary cell, the electrode that, in effect,
oxidizes the anode or absorbs the electrons.
Cell --
An electrochemical device, composed of positive and negative plates,
separator, and electrolyte, which is capable of storing electrical
energy. When encased in a container and fitted with terminals,
it is the basic "building block" of a battery.
Charge
-- Applied to a storage battery, the conversion of electric energy
into chemical energy within the cell or battery. This restoration
of the active materials is accomplished by maintaining a unidirectional
current in the cell or battery in the opposite direction to that
during discharge; a cell or battery which is said to be charged
is understood to be fully charged.
Charge Rate
-- The current applied to a secondary cell to restore its capacity.
This rate is commonly expressed as a multiple of the rated capacity
of the cell. For example, the C/10 charge rate of a 500 Ah cell
is expressed as,
C/10 rate = 500 Ah / 10 h = 50 A.
Charge, state of -- Condition of a cell in terms of the capacity
remaining in the cell.
Charging
-- The process of supplying electrical energy for conversion to
stored chemical energy.
Constant-Current
Charge -- A charging process in which the current of a
storage battery is maintained at a constant value. For some types
of lead-acid batteries this may involve two rates called the starting
and finishing rates.
Constant-Voltage
Charge -- A charging process in which the voltage of a
storage battery at the terminals of the battery is held at a constant
value.
Cycle
-- One sequence of charge and discharge. Deep cycling requires
that all the energy to an end voltage established for each system
be drained from the cell or battery on each discharge. In shallow
cycling, the energy is partially drained on each discharge; i.e.,
the energy may be any value up to 50%.
Cycle Life
-- For secondary rechargeable cells or batteries, the total number
of charge/discharge cycles the cell can sustain before it becomes
inoperative. In practice, end of life is usually considered to
be reached when the cell or battery delivers approximately 80%
of rated ampere-hour capacity.
Depth
of Discharge -- The relative amount of energy withdrawn
from a battery relative to how much could be withdrawn if the
battery were discharged until exhausted.
Discharge --
The conversion of the chemical energy of the battery into electric
energy.
Discharge, deep
-- Withdrawal of all electrical energy to the end-point voltage
before the cell or battery is recharged.
Discharge, high-rate
-- Withdrawal of large currents for short intervals of time, usually
at a rate that would completely discharge a cell or battery in
less than one hour.
Discharge, low-rate
-- Withdrawal of small currents for long periods of time, usually
longer than one hour.
Drain --
Withdrawal of current from a cell.
Dry Cell
-- A primary cell in which the electrolyte is absorbed in a porous
medium, or is otherwise restrained from flowing. Common practice
limits the term "dry cell" to the Leclanché cell,
which is the common commercial type.
Electrochemical
Couple -- The system of active materials within a cell
that provides electrical energy storage through an electrochemical
reaction.
Electrode
-- An electrical conductor through which an electric current enters
or leaves a conducting medium, whether it be an electrolytic solution,
solid, molten mass, gas, or vacuum. For electrolytic solutions,
many solids, and molten masses, an electrode is an electrical
conductor at the surface of which a change occurs from conduction
by electrons to conduction by ions. For gases and vacuum, the
electrodes merely serve to conduct electricity to and from the
medium.
Electrolyte
-- A chemical compound which, when fused or dissolved in certain
solvents, usually water, will conduct an electric current. All
electrolytes in the fused state or in solution give rise to ions
which conduct the electric current.
Electropositivity
-- The degree to which an element in a galvanic cell will function
as the positive element of the cell. An element with a large electropositivity
will oxidize faster than an element with a smaller electropositivity.
End-of-Discharge
Voltage -- The voltage of the battery at termination of
a discharge.
Energy
-- Output capability; expressed as capacity times voltage, or
watt-hours.
Energy Density
-- Ratio of cell energy to weight or volume (watt-hours per pound,
or watt-hours per cubic inch).
Float
Charging -- Method of recharging in which a secondary cell
is continuously connected to a constant-voltage supply that maintains
the cell in fully charged condition.
Galvanic
Cell -- A combination of electrodes, separated by electrolyte,
that is capable of producing electrical energy by electrochemical
action.
Gassing
-- The evolution of gas from one or both of the electrodes in
a cell. Gassing commonly results from self-discharge or from the
electrolysis of water in the electrolyte during charging.
Internal
Resistance -- The resistance to the flow of an electric
current within the cell or battery.
Memory
Effect -- A phenomenon in which a cell, operated in successive
cycles to the same, but less than full, depth of discharge, temporarily
loses the remainder of its capacity at normal voltage levels (usually
applies only to Ni-Cd cells).
Negative
Terminal -- The terminal of a battery from which electrons
flow in the external circuit when the cell discharges.
Nonaqueous Batteries -- Cells that
do not contain water, such as those with molten salts or organic
electrolytes.
Ohm's
Law -- The formula that describes the amount of current
flowing through a circuit. Voltage = Current × Resistance.
Open Circuit
-- Condition of a battery which is neither on charge nor on discharge
(i.e., disconnected from a circuit).
Open-Circuit
Voltage -- The difference in potential between the terminals
of a cell when the circuit is open (i.e., a no-load condition).
Oxidation
-- A chemical reaction that results in the release of electrons
by an electrode's active material.
Parallel
Connection -- The arrangement of cells in a battery made
by connecting all positive terminals together and all negative
terminals together, the voltage of the group being only that of
one cell and the current drain through the battery being divided
among the several cells. See Series Connection.
Polarity
-- Refers to the charges residing at the terminals of a battery.
Positive Terminal
-- The terminal of a battery toward which electrons flow through
the external circuit when the cell discharges.
Primary Battery
-- A battery made up of primary cells. See Primary Cell.
Primary Cell
-- A cell designed to produce electric current through an electrochemical
reaction that is not efficiently reversible. Hence the cell, when
discharged, cannot be efficiently recharged by an electric current.
Note: When the available energy drops to zero, the cell is usually
discarded. Primary cells may be further classified by the types
of electrolyte used.
Rated
Capacity -- The number of ampere-hours a cell can deliver
under specific conditions (rate of discharge, end voltage, temperature);
usually the manufacturer's rating.
Rechargeable
-- Capable of being recharged; refers to secondary cells or batteries.
Recombination
-- State in which the gasses normally formed within the battery
cell during its operation, are recombined to form water.
Reduction
-- A chemical process that results in the acceptance of electrons
by an electrode's active material.
Seal
-- The structural part of a galvanic cell that restricts the escape
of solvent or electrolyte from the cell and limits the ingress
of air into the cell (the air may dry out the electrolyte or interfere
with the chemical reactions).
Secondary Battery
-- A battery made up of secondary cells. See Storage Battery;
Storage Cell.
Self Discharge
-- Discharge that takes place while the battery is in an open-circuit
condition.
Separator
-- The permeable membrane that allows the passage of ions, but
prevents electrical contact between the anode and the cathode.
Series Connection
-- The arrangement of cells in a battery configured by connecting
the positive terminal of each successive cell to the negative
terminal of the next adjacent cell so that their voltages are
cumulative. See Parallel Connection.
Shelf Life
-- For a dry cell, the period of time (measured from date of manufacture),
at a storage temperature of 21°C (69°F), after which the
cell retains a specified percentage (usually 90%) of its original
energy content.
Short-Circuit
Current -- That current delivered when a cell is short-circuited
(i.e., the positive and negative terminals are directly connected
with a low-resistance conductor).
Starting-Lighting-Ignition
(SLI) Battery -- A battery designed to start internal combustion
engines and to power the electrical systems in automobiles when
the engine is not running. SLI batteries can be used in emergency
lighting situations.
Stationary Battery
-- A secondary battery designed for use in a fixed location.
Storage Battery
-- An assembly of identical cells in which the electrochemical
action is reversible so that the battery may be recharged by passing
a current through the cells in the opposite direction to that
of discharge. While many non-storage batteries have a reversible
process, only those that are economically rechargeable are classified
as storage batteries. Synonym: Accumulator; Secondary Battery.
See Secondary Cell.
Storage Cell
-- An electrolytic cell for the generation of electric energy
in which the cell after being discharged may be restored to a
charged condition by an electric current flowing in a direction
opposite the flow of current when the cell discharges. Synonym:
Secondary Cell. See Storage Battery.
Taper
Charge -- A charge regime delivering moderately high-rate
charging current when the battery is at a low state of charge
and tapering the current to lower rates as the battery becomes
more fully charged.
Terminals
-- The parts of a battery to which the external electric circuit
is connected.
Thermal Runaway
-- A condition whereby a cell on charge or discharge will destroy
itself through internal heat generation caused by high overcharge
or high rate of discharge or other abusive conditions.
Trickle Charging
-- A method of recharging in which a secondary cell is either
continuously or intermittently connected to a constant-current
supply that maintains the cell in fully charged condition.
Vent
-- A normally sealed mechanism that allows for the controlled
escape of gases from within a cell.
Voltage, cutoff
-- Voltage at the end of useful discharge. (See Voltage, end-point.)
Voltage, end-point
-- Cell voltage below which the connected equipment will not operate
or below which operation is not recommended.
Voltage, nominal
-- Voltage of a fully charged cell when delivering rated current.
Wet
Cell -- A cell, the electrolyte of which
is in liquid form and free to flow and move.
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